Electrolyte acidification from anode reactions during lithium mediated ammonia synthesis

نویسندگان

چکیده

Li-mediated electrochemical ammonia synthesis (LiMEAS), a potential alternative to conventional thermochemical synthesis, is enabled by non-aqueous electrolytes with precisely controlled proton activity. However, the effects of generating anode reactions, such as hydrogen or electrolyte oxidation, unknown but crucially important for enabling steady-state LiMEAS without need sacrificial sources. By employing cyclic voltammetry on platinum electrode, we demonstrate that protons are generated not only oxidation also which has consequence continuous acidification over course experiment. In addition, voltammograms reveal show reactivity towards components, would disrupt replenishment added source. We therefore suggest design new contain acceptors, ultimately resulting in buffered stable

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A Review of Solid Electrolyte Interphases on Lithium Metal Anode

Lithium metal batteries (LMBs) are among the most promising candidates of high-energy-density devices for advanced energy storage. However, the growth of dendrites greatly hinders the practical applications of LMBs in portable electronics and electric vehicles. Constructing stable and efficient solid electrolyte interphase (SEI) is among the most effective strategies to inhibit the dendrite gro...

متن کامل

Solid Electrolyte Interphase Formation on Silicon and Lithium Titanate Anode Materials in Lithium-Ion Batteries

Aiming at an improved knowledge of the formation of the solid electrolyte interphase (SEI), as basis for the safe and efficient use of new anode materials, we investigated the SEI formation on silicon and lithium titanate (LTO) anodes by electrochemical impedance spectroscopy (EIS) and ex situ X-ray photoelectron spectroscopy (XPS) measurements. While the EIS measurements performed at equidista...

متن کامل

Electrochemical Synthesis of Ammonia in Solid Electrolyte Cells

*Correspondence: Michael Stoukides, Department of Chemical Engineering, Aristotle University of Thessaloniki, Building E13, Laboratory of Electrochemical Processes, Thessaloniki 54124, Greece e-mail: [email protected] Developed in the early 1900s, the “Haber–Bosch” synthesis is the dominant NH3 synthesis process. Parallel to catalyst optimization, current research efforts are also focused...

متن کامل

NMR Study of the Solid Electrolyte Interface on a High Performance Lithium Metal Anode

Introduction: Li metal is an ideal anode material due to its low density (0.534 g cm -3 ), the lowest negative electrochemical potential (-3.040 V vs. standard hydrogen electrode) and extremely high theoretical special capacity (3860 mAh g -1 ), which is ten times as high as that of carbonaceous materials. However, several seemingly insurmountable barriers, including limited Columbic efficiency...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Electrochemistry Communications

سال: 2022

ISSN: ['1388-2481', '1873-1902']

DOI: https://doi.org/10.1016/j.elecom.2021.107186